I’m very fond of “ranking problems” that ask students to order a series of compounds in some way and provide an explanation. One of my all-time favorites is the famous “rank these acids from most to least acidic…” problem, which might include compounds like the following.
To really understand a problem like this deeply, the student has to be able to connect the structures provided with either physical/chemical properties or theoretical constructs (such as electron-donating and electron-withdrawing groups). Structure-property relationships are at the root of the appropriate thinking here. Unfortunately, as was pointed out by a recent paper that caught my attention in J. Res. Sci. Teach., students often struggle with structure-property relationships. Without experience under one’s belt, the incredible utility packed into a Lewis structure can be lost on students. It’s staggering, really—what other devices in science approach the information density of a chemical structure?!
I wanted to comment on this paper because it resonated with me. The authors explored the prior knowledge and heuristics that students used to rank the thermodynamic favorability of a series of chemical reactions. The work is a small piece of a larger movement that explores how chemists both novice and expert make judgments and decisions when solving problems.
I imagine that work in this field gets messy and discouraging very quickly. Novices are inclined to rely on unconvincing, arbitrary, or otherwise spurious assumptions. Is it worth drawing attention to these bogus ideas that guide students’ thought processes? That remains an open question, but I’d say that to conquer a problem, one must first hold it up to the light. As painful as it may be to learn just how little instruction affects students’ intuitive assumptions, “the first step is admitting you have a problem.” Chemistry experts, by the way, aren’t immune—just as many experts have trouble verbalizing their thought processes when navigating by feel!
In the paper, Maeyer and Talanquer studied problems related to acid-base chemistry, elemental synthesis, and combustion. They asked students to order sets of three related reactions from most favorable to least favorable in a thermodynamic sense. Qualitative interviews of a small set of students (33) supplemented large-scale survey data. The results were typical: a small number of students (less than 35%, generally) actively verbalized what the authors called valid chemical assumptions while rationalizing their orderings. Many more employed either intuitive assumptions that had at their core ideas completely unrelated to chemistry (“bigger things are harder to make than smaller things”) or spurious chemical assumptions with no basis in chemical theory but employing concepts from chemical theory (“electronegative atoms are more reactive”; bogus periodic trends).
With fascinating results, the authors also explored the heuristics students used to come to a decision. A majority of students focused on a single factor that they presumed to be the essence of the difference between the reactions—the authors called this the one-reason decision-making (ORDM) heuristic. The recognition heuristic played an important role, as many students stuck at the top or bottom of their lists reactions that involved familiar species (“Ooh, I’ve seen NaCl before, so its precipitation from water must be favorable”). Some students cited artificial correlations between variables, a strategy the authors called more A-more B (“Na to Ca to Al goes from +1 to +3, so I’m going to put them in this order”). Finally, the authors identified a representativeness heuristic that involved grouping items based on explicit similarities (“Cl and I in HCl and HI have the same charge, so I’m putting them next to each other in the list. S in H2S has different charge, so I’m putting it at the bottom of the list.”).
Painful to read, isn’t it? Many of the students generated correct orderings, but for all kinds of bogus reasons. Rather like buying your girlfriend flowers on Valentine’s Day because of a fight the night before…not exactly playing Casanova there! Of course, not all of the assumptions and reasoning strategies are bad. For example, ORDM reflects an analytical approach that teases out all the important differences between the reactions—the trick is weighing the differences against one another carefully instead of betting it all on a single factor.
Maeyer and Talanquer harbor no illusions concerning the generality of their work. Many times in their paper, as is typical of qualitative research articles in chemical education, they remark that the work used a small sample and lacks generality without further study. I think the work is still valuable for at least two reasons: (1) their framework of assumptions/heuristics provides a useful lens for diagnosing problems in the thought processes of students; and (2) it invites teachers young and old to take off their rose-colored glasses and reconsider how they teach. I don’t know about you, but I’d rather read about students’ issues with chemical reasoning before encountering it in my own classroom! This paper is one in a long line of studies that paint a descriptive picture of students’ chemical reasoning processes, and many more are to come. That’s “descriptive” as opposed to “prescriptive”: what “is” rather than what “ought to be” (although interestingly, Maeyer and Talanquer devote half a page to what ought to be in the form of the “target reasoning process”).
There are interesting parallels to ethics and philosophy here: should chemistry education researchers be focusing on what is rather than what ought to be? Why waste time on the way things are when we have so much to say to students about how they ought to think? Clearly, that “so much to say” doesn’t have as great an impact as we think it does—studies like this one demonstrate that convincingly. But will studying the way things are help us advance teaching and learning in a lasting way? I’m not sure. What do you think?
Here’s the full paper.